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Sulforaphane, generated from glucoraphanin upon chopping or chewing, potently activates the Nrf2 transcriptional pathway, increasing glutathione synthesis and enhancing neuronal resilience against oxidative injury (171–176)
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Notably, free Trp was found to form both melanin and kynurenine (Kyn) as photooxidation products, whereas Trp residues in peptides were predominantly converted to Kyn, with yields reaching up to ~98%
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